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Synthesis of (±)-Epoxysorbicillinol Using a Novel Cyclohexa-2,5-dienone with Synthetic Applications to Other Sorbicillin Derivatives
[Image: see text] A novel route to epoxysorbicillinol as well as dimers of sorbicillin is reported. The synthesis is—in principle—amenable to enantioselectivity. The key step is an oxidative dearomatization to produce a stable and highly malleable p-quinol intermediate, which undergoes a highly dias...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2001
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1360178/ https://ncbi.nlm.nih.gov/pubmed/11263912 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0155438 |
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