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Discovery of a reaction intermediate of aliphatic aldoxime dehydratase involving heme as an active center

Recently, we discovered an intriguing hemoprotein [aliphatic aldoxime dehydratase (OxdA)] that catalyzes the dehydration of aliphatic aldoximes [R–CH=N–OH] to the corresponding nitriles [R–C≡N] in the industrial Pseudomonas chlororaphis B23 strain. Unlike the utilization of H(2)O(2) or O(2) as a med...

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Détails bibliographiques
Auteurs principaux: Konishi, Kazunobu, Ohta, Takehiro, Oinuma, Ken-Ichi, Hashimoto, Yoshiteru, Kitagawa, Teizo, Kobayashi, Michihiko
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2006
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC1334632/
https://ncbi.nlm.nih.gov/pubmed/16407114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0505412103
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