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Resonance Raman Studies of Co—O(2) and O—O Stretching Vibrations in Oxy-Cobalt Hemes
Strong evidence suggests that the stretching vibration of the bound oxygen can be perturbed by an accidentally degenerate porphyrin ring mode, resulting in two split frequencies. In the Co(II)(TpivPP) (pyridine) (18)O(2) complex, we demonstrate that the ν((18)O—(18)O) mode, after being shifted from...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1983
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1329188/ https://ncbi.nlm.nih.gov/pubmed/6838973 |
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