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Diffusion-controlled bimolecular reaction rates. The effect of rotational diffusion and orientation constraints.

A new approach to the calculation of bimolecular association constants for partially diffusion-limited reactions between asymmetric species (e.g. the ligand binding site of a macromolecule covers only a portion of its surface) is presented. The usual formulation, which is almost always analytically...

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Bibliographic Details
Main Authors: Shoup, D, Lipari, G, Szabo, A
Format: Artigo
Language:Inglês
Published: 1981
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC1327653/
https://ncbi.nlm.nih.gov/pubmed/7326330
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