Modulation of the electronic structure and the Ni–Fe distance in heterobimetallic models for the active site in [NiFe]hydrogenase

Reaction of the mononuclear Ni(II) thiolate complexes [Ni(L)] [L, L(1), H(2)L(1), bis(2-mercaptoethyl)-1,2-dimercaptoethane; L(2), H(2)L(2), N,N′-dimethyl-N,N′-bis(2-mercaptoethyl)-bis(aminoethyl)sulfide] with [FeCp(CO)(2)I] gives the dithiolate-bridged heterobimetallic species, [Ni(L(1))FeCp(CO)]PF...

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Bibliographic Details
Main Authors: Zhu, Wenfeng, Marr, Andrew C., Wang, Qiang, Neese, Frank, Spencer, Douglas J. E., Blake, Alexander J., Cooke, Paul A., Wilson, Claire, Schröder, Martin
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2005
Subjects:
Physical Sciences
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC1317917/
https://ncbi.nlm.nih.gov/pubmed/16352727
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0505779102
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