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Probing Electric Fields in Protein Cavities by Using the Vibrational Stark Effect of Carbon Monoxide
To determine the magnitude and direction of the internal electric field in the Xe4 cavity of myoglobin mutant L29W-S108L, we have studied the vibrational Stark effect of carbon monoxide (CO) using infrared spectroscopy at cryogenic temperatures. CO was photodissociated from the heme iron and deposit...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Biophysical Society
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1305250/ https://ncbi.nlm.nih.gov/pubmed/15596507 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1529/biophysj.104.048140 |
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