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Ligand dynamics in the photodissociation of carboxyhemoglobin by subpicosecond transient infrared spectroscopy.

Time-resolved infrared spectroscopy with 0.5-ps resolution is used to track the evolution of the CO stretching vibration after visible photoexcitation of carboxyhemoglobin in water at room temperature. Polarization measurements determine that the iron-complexed CO is oriented nearly perpendicular to...

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Bibliographic Details
Main Authors: Rothberg, L, Jedju, T M, Austin, R H
Format: Artigo
Language:Inglês
Published: 1990
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC1280677/
https://ncbi.nlm.nih.gov/pubmed/2317555
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