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Substituent effects on cation–π interactions: A quantitative study

A synthetic supramolecular complex has been adapted to quantify cation–π interactions in chloroform by using chemical double-mutant cycles. The interaction of a pyridinium cation with the π-face of an aromatic ring is found to be very sensitive to the π-electron density. Electron-donating substituen...

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Bibliografiske detaljer
Main Authors: Hunter, Christopher A., Low, Caroline M. R., Rotger, Carmen, Vinter, Jeremy G., Zonta, Cristiano
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2002
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC122686/
https://ncbi.nlm.nih.gov/pubmed/11959939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.072647899
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