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Substituent effects on cation–π interactions: A quantitative study
A synthetic supramolecular complex has been adapted to quantify cation–π interactions in chloroform by using chemical double-mutant cycles. The interaction of a pyridinium cation with the π-face of an aromatic ring is found to be very sensitive to the π-electron density. Electron-donating substituen...
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| Hlavní autoři: | , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
National Academy of Sciences
2002
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC122686/ https://ncbi.nlm.nih.gov/pubmed/11959939 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.072647899 |
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