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The effect of iron displacement out of the porphyrin plane on the resonance Raman spectra of heme proteins and iron porphyrins.
The causes of the strong coupling of the iron-histidine vibration to the Soret resonance in the resonance Raman spectra of deoxyhemoglobin, myoglobin, and peroxidase are explored, using the vibronic theory. It is shown that the extent of the iron displacement out of the plane of the porphyrin nitrog...
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| Autor principal: | |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1993
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1225929/ https://ncbi.nlm.nih.gov/pubmed/8298023 |
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