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Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe(4)S(4)](0) cluster of the nitrogenase iron protein
The synthetic cubane-type iron–sulfur clusters [Fe(4)S(4)(SR)(4)](z) form a four-member electron transfer series (z = 3–, 2–, 1–, and 0), all members of which except that with z = 0 have been isolated and characterized. They serve as accurate analogues of protein-bound [Fe(4)S(4)(SCys)(4)](z) redox...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1175011/ https://ncbi.nlm.nih.gov/pubmed/15985547 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0504258102 |
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