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Semisynthetic analogues of insulin. The use of N-substituted derivatives of methionine as acid-stable protecting groups

1. We describe the use of benzyloxycarbonylmethionine and ethoxycarbonylmethionine for the selective protection of the amino groups of glycine-A1 and lysine-B29 of pig insulin. We have used the Edman method to remove residues from the N-terminal and of the B-chain of the N(A1)N(B29)-di-protected der...

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Autors principals: Saunders, Derek J., Offord, Robin
Format: Artigo
Idioma:Inglês
Publicat: 1977
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC1164930/
https://ncbi.nlm.nih.gov/pubmed/921761
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