Fully Oxidized and Mixed-Valent Polyoxomolybdates Structured by Bisphosphonates with Pendant Pyridine Groups: Synthesis, Structure and Photochromic Properties

Hybrid organic-inorganic polyoxometalates (POMs) were synthesized in water by the reaction of a MoVI precursor with bisphosphonate ligands functionalized by pyridine groups. The fully oxidized POM [(MoVI3O8)2(O)(O3PC(O)(C3H6NH2CH2C5H4NH)PO3)2]4− has been isolated as water insoluble pure Na salt (NaM...

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Main Authors: Olivier Oms, Tarik Benali, Jérome Marrot, Pierre Mialane, Marin Puget, Hélène Serier-Brault, Philippe Deniard, Rémi Dessapt, Anne Dolbecq
Formato: Artigo
Idioma:Inglês
Publicado: MDPI AG 2015-06-01
Series:Inorganics
Assuntos:
bisphosphonate
hydrogen bonds
molybdenum
photochromism
polyoxometalate
Acceso en liña:http://www.mdpi.com/2304-6740/3/2/279
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