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Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO2–MEA absorptions with CaCO3, MgCO3 and BaCO3

The mechanism was proposed of heterogeneous catalytic CO2 absorptions with primary/secondary amines involving ‘catalytic carbamate formation’. Compared with the non-catalytic ‘Zwitterion mechanism’, this Eley–Rideal model was proposed for CO2 + RR′NH with MCO3 (M = Ca, Mg, and Ba) with four elementa...

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Hlavní autoři: Huancong Shi, Min Huang, Yuandong Huang, Lifeng Cui, Linna Zheng, Mingqi Cui, Linhua Jiang, Hussameldin Ibrahim, Paitoon Tontiwachwuthikul
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society 2019-05-01
Edice:Royal Society Open Science
Témata:
co2 absorption and desorption
heterogeneous catalysis
eley–rideal model
zwitterion mechanism
solid surface reactions
On-line přístup:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190311
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