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Cycloaddition of Benzyne with Alkoxy-Substituted Pyrroline-N-oxides: Unexpected Rearrangement to an N-Phenylpyrrole
Abstract Reaction of enantiopure 3,4-dialkoxy-pyrroline N-oxides with benzyne affords the expected tetrahydrobenzo[d]pyrrolo[1,2-b]isoxazoles along with an unexpected 2,3-disubstitued-N-phenyl-pyrrole derived from an unprecedented rearrangement of the adduct of nitrone with two molecules of benzyne....
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Georg Thieme Verlag KG
2018-01-01
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| Colecção: | SynOpen |
| Assuntos: | |
| Acesso em linha: | http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1609082 |
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