Synthesis and Characterization of N,N,O-Tridentate Aminophenolate Zinc Complexes and Their Catalysis in the Ring-Opening Polymerization of Lactides

A series of aminophenolate ligands with various pendant groups and associated ethyl Zn complexes were synthesized and studied as catalysts for the ring-opening polymerization (ROP) of lactides (LAs). The thiophenylmethyl group (L4ZnEt) increased the catalytic activity more than the benzyl group (L1Z...

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Autores principales: Wei-Yi Lu, Kuo-Hui Wu, Hsuan-Ying Chen, Chu-Chieh Lin
Formato: Artigo
Lenguaje:Inglês
Publicado: Frontiers Media S.A. 2019-04-01
Colección:Frontiers in Chemistry
Materias:
zinc
polymerization
catalyst
lactide
kinetic
Acceso en línea:https://www.frontiersin.org/article/10.3389/fchem.2019.00189/full
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