Reactivity of Myoglobin Reconstituted with Cobalt Corrole toward Hydrogen Peroxide

The protein matrix of natural metalloenzymes regulates the reactivity of metal complexes to establish unique catalysts. We describe the incorporation of a cobalt complex of corrole (CoCor), a trianionic porphyrinoid metal ligand, into an apo-form of myoglobin to provide a reconstituted protein (rMb(...

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Bibliographic Details
Main Authors: Koji Oohora, Hirotaka Tomoda, Takashi Hayashi
Format: Artigo
Language:Inglês
Published: MDPI AG 2022-04-01
Series:International Journal of Molecular Sciences
Subjects:
porphyrinoid
metalloprotein
oxidation
Online Access:https://www.mdpi.com/1422-0067/23/9/4829
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