The impact of crystal size and temperature on the adsorption-induced flexibility of the Zr-based metal–organic framework DUT-98

In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature on the switching behavior of the flexible Zr-based metal–organic framework DUT-98. We observe a shift in the gate-opening pressure upon cycling of adsorption experiments for micrometer-sized crystals a...

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Detalhes bibliográficos
Main Authors: Simon Krause, Volodymyr Bon, Hongchu Du, Rafal E. Dunin-Borkowski, Ulrich Stoeck, Irena Senkovska, Stefan Kaskel
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2019-08-01
Colecção:Beilstein Journal of Nanotechnology
Assuntos:
crystal engineering
crystal size
flexible metal–organic frameworks
MOFs
water adsorption
Acesso em linha:https://doi.org/10.3762/bjnano.10.169
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