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The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase.

In this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to...

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Principais autores: E. V. Fesik, V. V. Grebnev, G. D. Malchikov
Formato: Artigo
Idioma:Russo
Publicado em: MIREA - Russian Technological University 2008-06-01
coleção:Тонкие химические технологии
Acesso em linha:https://www.finechem-mirea.ru/jour/article/view/1503
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