Polymers of ε-Caprolactone Using New Copper(II) and Zinc(II) Complexes as Initiators: Synthesis, Characterization and X-Ray Crystal Structures

Five of six new Zn(II) and Cu(II) complexes were active in the ring-opening polymerization (ROP) of &#949;-caprolactone (CL) under solvent-free conditions, producing polycaprolactones (PCLs) of high crystallinity with molecular weights between 22,900 and 38,700 g mol<sup>&#8722;1</s...

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Detalhes bibliográficos
Main Authors: Andrés F. Posada, Mario A. Macías, Santiago Movilla, Gian Pietro Miscione, León D. Pérez, John J. Hurtado
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2018-11-01
Colecção:Polymers
Assuntos:
ring-opening polymerization
ε-caprolactone
bis(3,5-dimethylpyrazole) ligands
zinc(II) and copper(II) complexes
crystal structures
Acesso em linha:https://www.mdpi.com/2073-4360/10/11/1239
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