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Kinetic Stabilization of [n]Cumulenes by Endgroup Design

The quest to model carbyne has been largely tackled through increasingly longer polyynes. [n]Cumulenes are an alternative class of molecules to model carbyne. The major difference between polyynes and cumulenes is that polyynes maintain strong bond length alternation (BLA) while cumulenes do not. Th...

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Autores principales: Bozheng Sun, Matthew A. Johnson, Marc H. Garner, Dominik Wendinger, Yanwen Yang, Lanting Jiang, Michael J. Ferguson, Rik R. Tykwinski
Formato: Artigo
Lenguaje:Inglês
Publicado: Wiley-VCH 2026-02-01
Colección:ChemistryEurope
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Acceso en línea:https://doi.org/10.1002/ceur.202500406
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