Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh<sub>3</sub>)(Br)]<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>, [Pd(Br)]<sub>2</sub>(μ,η<sup>2</sup>-Hdppa)<sub>2</sub>, and [{Pd(PPh<sub>3</sub>)(CH<sub>3</sub>CN)}<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>][BF<sub>4</sub>]<sub>2</sub>
In a refluxing chloroform solution, the η<sup>1</sup>-pyrimidinyl {pyrimidinyl = C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>} palladium complex [Pd(PPh<sub>3</sub>)<sub>2</sub>(η<sup>1</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)(Br)], <b>1</b> exhibited intermolecular displacement of two triphenylpho...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
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MDPI AG
2020-04-01
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| Schriftenreihe: | Molecules |
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| Online-Zugang: | https://www.mdpi.com/1420-3049/25/9/2035 |
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