Triggering of Valence Tautomeric Transitions in Dioxolene-Based Cobalt Complexes Influenced by Ligand Substituents, Co-ligands, and Anions

We report the multistep synthesis of the 1,1′-(piperazine-1,4-diyl)bis(N,N-bis(pyridin-2-ylmethyl)methanamine)(<b>L^tpbap</b>) octadentate ligand, which, in combination with the known 3,5-di-tert-butylcatechol (<b>3,5-dbcat</b>), allowed the preparation of two di-nuclear cobalt complexes [...

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Detalhes bibliográficos

Principais autores:	Sriram Sundaresan, Marcel Diehl, Luca M. Carrella, Eva Rentschler
Formato:	Artigo
Idioma:	Inglês
Publicado em:	MDPI AG 2022-09-01
Colecção:	Magnetochemistry
Assuntos:	Valence-Tautomer cobalt di-nuclear di-oxolene
Acesso em linha:	https://www.mdpi.com/2312-7481/8/9/109
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