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Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities

The Pd(II) complexes [Pd(Cp)(L)<sub>n</sub>]<sub>m</sub>[BF<sub>4</sub>]<sub>m</sub> were synthesized via the reaction of cationic acetylacetonate complexes with cyclopentadiene in the presence of BF<sub>3</sub>∙OEt<sub>2</sub> (<i>n</i> = 2, <i>m</i> = 1: L = PPh<sub>3</sub> (<b>1</b>), P(<i>p</i>-...

Ausführliche Beschreibung

Gespeichert in:
Hauptverfasser: Dmitry S. Suslov, Mikhail V. Bykov, Marina V. Pakhomova, Timur S. Orlov, Zorikto D. Abramov, Anastasia V. Suchkova, Igor A. Ushakov, Pavel A. Abramov, Alexander S. Novikov
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI AG 2023-05-01
Schriftenreihe:Molecules
Schlagworte:
palladium
cyclopentadienyl
acetylacetonate
1,3-butadiene
telomerization
phenylacetylene
Online-Zugang:https://www.mdpi.com/1420-3049/28/10/4141
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