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Ru-Controlled Thymine Tautomerization Frozen by a k<sup>1</sup>(O)-, k<sup>2</sup>(N,O)-Metallacycle: An Experimental and Theoretical Approach

The reaction of <i>mer</i>-(Ru(H)<sub>2</sub>(CO)(PPh<sub>3</sub>)<sub>3</sub>) (<b>1</b>) with one equivalent of thymine acetic acid (THAcH) unexpectedly produces the macrocyclic dimer k<sup>1</sup>(O), k<sup>2</sup>(N,O)-(Ru(CO)(PPh<sub>3</sub>)<sub>2</sub>THAc)<sub>2</sub> (<b>4</b>) and, concomi...

Deskribapen osoa

Gorde:
Egile Nagusiak: Silvia Bordoni, Riccardo Tarroni, Magda Monari, Stefano Cerini, Fabio Battaglia, Gabriele Micheletti, Carla Boga, Giacomo Drius
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: MDPI AG 2023-05-01
Saila:Molecules
Gaiak:
ruthenium
Ru(II)
thymine
(N,O) chelation
self-assembly
X-ray crystal structure
Sarrera elektronikoa:https://www.mdpi.com/1420-3049/28/10/3983
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