Ruthenium redox equilibria: 2. Thermodynamic analysis of disproportionation and comproportionation conditions

The key property of Frost diagram has been confirmed using thermodynamic and linear algebra methods. On the basis of the thermodynamic data, the areas of thermodynamic stability of ruthenium chemical species in different valence states as a function of pH for each degree of oxidation have been deter...

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Detalhes bibliográficos

Principais autores:	Igor Povar, Oxana Spinu
Formato:	Artigo
Idioma:	Inglês
Publicado em:	International Association of Physical Chemists (IAPC) 2016-04-01
coleção:	Journal of Electrochemical Science and Engineering
Assuntos:	Disproportionation and comproportionation equilibria revised Frost diagram reduced Gibbs energy of half reaction of oxidation ruthenium soluble and insoluble species.
Acesso em linha:	http://pub.iapchem.org/ojs/index.php/JESE/article/view/228
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