The efficient synthesis of dibenzo[d,d′]benzo[1,2-b:4,3-b′]dithiophene and cyclopenta[1,2-b:4,3-b′]bis(benzo[d]thiophen)-6-one

With 3,3′-bi[benzo[b]thiophenyl] as starting material, dibenzo[d,d′]benzo[1,2-b:4,3-b′]dithiophene, a [5]heterohelicene, was synthesized efficiently in 60% yield via formylation and McMurry reaction. Cyclopenta[1,2-b:4,3-b′]bis(benzo[d]thiophen)-6-one, another interesting helical ketone, was also pr...

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Detalhes bibliográficos

Principais autores:	Zhihua Wang, Sheng Zhu, Jianwu Shi, Hua Wang
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Beilstein-Institut 2009-10-01
coleção:	Beilstein Journal of Organic Chemistry
Assuntos:	crystal structure cyclopenta[1,2-b:4,3-b′]bis(benzo[d]thiophen)-6-one dibenzo[d,d′]benzo[1,2-b:4,3-b′]dithiophene McMurry reaction preparation
Acesso em linha:	https://doi.org/10.3762/bjoc.5.55
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