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Quantum Chemical and Experimental Studies of an Unprecedented Reaction Pathway of Nucleophilic Substitution of 2-Bromomethyl-1,3-thiaselenole with 1,3-Benzothiazole-2-thiol Proceeding Stepwise at Three Different Centers of Seleniranium Intermediates

The results of quantum chemical and experimental studies of the reaction of 2-bromomethyl-1,3-thiaselenole with 1,3-benzothiazole-2-thiol made it possible to discover the unprecedented pathway of this reaction, which proceeds stepwise at three different centers of seleniranium intermediates. The fir...

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Principais autores: Svetlana V. Amosova, Vladimir A. Shagun, Nataliya A. Makhaeva, Irina A. Novokshonova, Vladimir A. Potapov
Formato: Artigo
Idioma:Inglês
Publicado: MDPI AG 2021-11-01
Series:Molecules
Assuntos:
2-bromomethyl-1,3-thiaselenole
1,3-benzothiazole-2-thiol
vinyl sulfides
2,3-dihydro-1,4-thiaselenine
seleniranium cation
rearrangement
Acceso en liña:https://www.mdpi.com/1420-3049/26/21/6685
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