Energy Transfer Catalysis Enabled 2,2,2‐Trifluoroethoxy‐Amination of Olefins

A thioxanthone‐catalyzed 2,2,2‐trifluoroethoxyamination of olefins is developed via the formation of the corresponding alkoxy and iminyl radicals using unprecedented, easily prepared, and bench‐stable oxime ethers as bifunctional reagents. To bypass possible side reactions (1,2‐Hydrogen Atom Transfe...

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Autors principals:	Floriane Doche, Thibault Gallavardin, Thomas Poisson, Tatiana Besset
Format:	Artigo
Idioma:	Inglês
Publicat:	Wiley-VCH 2025-07-01
Col·lecció:	ChemistryEurope
Matèries:	alkoxy radical generation bifunctional reagents energy transfer photocatalysis 2,2,2‐trifluoroethoxyamination reactions
Accés en línia:	https://doi.org/10.1002/ceur.202500041
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