Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished. The catalytic reactions proceeded under mild reaction conditions, providing the corresponding aromatic trifluoromethylated...

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Bibliografische Detailangaben

Hauptverfasser:	Yuzo Nakamura, Motohiro Fujiu, Tatsuya Murase, Yoshimitsu Itoh, Hiroki Serizawa, Kohsuke Aikawa, Koichi Mikami
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	Beilstein-Institut 2013-11-01
Schriftenreihe:	Beilstein Journal of Organic Chemistry
Schlagworte:	organo-fluorine Ruppert–Prakash reagent trifluoromethyl trifluoromethylation trifluoromethyl zinc
Online-Zugang:	https://doi.org/10.3762/bjoc.9.277
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