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Quantitative Explanation of Retention Mechanisms of Hydrophobic and Hydrophilic-Interaction Liquid Chromatography-Inductive Effect of Alkyl Chain

The basic retention mechanisms of reversed-phase and hydrophilic-interaction liquid chromatography (HILIC) were quantitatively analyzed using simple molecular mechanics (MM) calculations. The model bonded phases were composed of an alkyl chain bonded to siloxane-like molecules. The head of the alkyl...

Ausführliche Beschreibung

Gespeichert in:
1. Verfasser: Toshihiko Hanai
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI AG 2017-11-01
Schriftenreihe:Separations
Schlagworte:
retention mechanism
hydrophobic interaction
hydrophilic interaction
inductive effect of alkyl chain
computational chemistry
Online-Zugang:https://www.mdpi.com/2297-8739/4/4/33
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