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The Conversion of Superoxide to Hydroperoxide on Cobalt(III) Depends on the Structural and Electronic Properties of Azole-Based Chelating Ligands

Conversion from superoxide (O<sub>2</sub><sup>−</sup>) to hydroperoxide (OOH<sup>−</sup>) on the metal center of oxygenases and oxidases is recognized to be a key step to generating an active species for substrate oxidation. In this study, reactivity of cobalt(III)-superoxido complexes supported by...

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Principais autores: Toshiki Nishiura, Takehiro Ohta, Takashi Ogura, Jun Nakazawa, Masaya Okamura, Shiro Hikichi
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2022-09-01
coleção:Molecules
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Acesso em linha:https://www.mdpi.com/1420-3049/27/19/6416
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