Nickel(II)-polypyridine complexes: bridging XPS insights with DFT calculations
The electrochemical oxidation of a series of tris(polypyridine)nickel(II) complexes (1–8) yields Ni(III) species with oxidation potentials (E1/2) showing a direct correlation to the Ni 2p3/2 binding energy (BE) determined by XPS. Higher oxidation potential correspond to increased binding energies, i...
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| Principais autores: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Elsevier
2026-08-01
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| Serier: | Results in Chemistry |
| Fag: | |
| Online adgang: | http://www.sciencedirect.com/science/article/pii/S2211715626005126 |
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