Original Reactivity of ?-Diazo-?- ketoesters Catalyzed by CpRu Complexes

Using ?-diazo-?-ketoesters as reagents and combinations of CpRu fragments and diimine ligands as catalysts, a series of original transformations have been obtained that can be rationalized by the formation of metal carbenes and metal-bound ylide intermediates. Interesting 1,3-dioxole, enol...

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Номзүйн дэлгэрэнгүй

Үндсэн зохиолчид:	Cecilia Tortoreto, Thierry Achard, Martina Austeri, Walid Zeghida, Jérôme Lacour
Формат:	Artigo
Хэл сонгох:	Alemão
Хэвлэсэн:	Swiss Chemical Society 2014-04-01
Цуврал:	CHIMIA
Нөхцлүүд:	Diazo compounds Insertions Metal carbenes Oxonium ylide
Онлайн хандалт:	https://www.chimia.ch/chimia/article/view/5551
Шошгууд:	Шошго нэмэх Шошго байхгүй, Энэхүү баримтыг шошголох эхний хүн болох!