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Ferric Chloride Promoted Glycosidation of Alkyl Thioglycosides

Reported herein is a new reaction for glycosylation with thioglycosides in the presence of iron(III) chloride. Previously, FeCl<sub>3</sub> was used for the activation of thioglycosides as a Lewis acid co-promoter paired with NIS. In the reported process, although 5.0 equiv of FeCl<sub>3</sub> are n...

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Principais autores: Lacie M. Ridgway, Anupama Das, Melanie L. Shadrick, Alexei V. Demchenko
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2024-10-01
Serier:Molecules
Fag:
glycosylation
ferric chloride
green chemistry
carbohydrates
thioglycosides
Online adgang:https://www.mdpi.com/1420-3049/29/20/4845
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