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Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation

A series of manganese complexes bearing an anionic pyrrole-based PNP-type pincer ligand and an anionic benzene-based PCP-type pincer ligand is synthesized and characterized. The reactivity of these complexes toward ammonia formation and silylamine formation from dinitrogen under mild conditions is e...

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Principais autores: Shogo Kuriyama, Shenglan Wei, Takeru Kato, Yoshiaki Nishibayashi
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2022-04-01
Serier:Molecules
Fag:
manganese
nitrogen fixation
pincer ligand
Online adgang:https://www.mdpi.com/1420-3049/27/7/2373
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