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Thermo-Reversible Persistent Phosphorescence Modulation Reveals the Large Contribution Made by Rigidity to the Suppression of Endothermic Intermolecular Triplet Quenching

The suppression of thermally driven triplet deactivation is crucial for efficient persistent room-temperature phosphorescence (pRTP). However, the mechanism by which triplet deactivation occurs in metal-free molecular solids at room temperature (RT) remains unclear. Herein, we report a large pRTP in...

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Principais autores: Tomoya Kusama, Shuzo Hirata
Format: Artigo
Sprog:Inglês
Udgivet: Frontiers Media S.A. 2021-11-01
Serier:Frontiers in Chemistry
Fag:
persistent room-temperature phosphorescence
triplet quenching
nonradiative deactivation
phase change
diffusion constant
reorganization energy
Online adgang:https://www.frontiersin.org/articles/10.3389/fchem.2021.788577/full
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