Extracting metal oxide redox thermodynamics from TGA measurements requires moving beyond the linearized van ‘t Hoff approach

Thermodynamic modeling of metal oxide reduction is crucial for optimizing chemical processes and materials in systems dependent on off-stoichiometric reduction/re-oxidation cycling. Two prevalent methods for extracting reduction thermodynamics from thermogravimetric data are linearized van ‘t Hoff (...

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Principais autores:	Steven A. Wilson, Paul W. Sarsam, Ellen B. Stechel, Christopher L. Muhich
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Frontiers Media S.A. 2024-10-01
coleção:	Frontiers in Energy Research
Assuntos:	chemical looping reduction thermodynamics solar thermochemical density funcational theory van ’t Hoff compound energy formalism
Acesso em linha:	https://www.frontiersin.org/articles/10.3389/fenrg.2024.1470010/full
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