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Gold-catalyzed reaction of oxabicyclic alkenes with electron-deficient terminal alkynes to produce acrylate derivatives

Oxabicyclic alkenes can react with electron-deficient terminal alkynes in the presence of a gold catalyst under mild conditions, affording the corresponding addition products in moderate yields. When using alkynyl esters as substrates, the (Z)-acrylate derivatives are obtained. Using but-3-yn-2-one...

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Bibliografische gegevens
Hoofdauteurs: Yin-wei Sun, Qin Xu, Min Shi
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Beilstein-Institut 2013-10-01
Reeks:Beilstein Journal of Organic Chemistry
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Online toegang:https://doi.org/10.3762/bjoc.9.233
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