Synthesis, Magnetic Properties, and Catalytic Properties of a Nickel(II)-Dependent Biomimetic of Metallohydrolases

A dinickel(II) complex of the ligand 1,3-bis(bis(pyridin-2-ylmethyl)amino)propan-2-ol (HL1) has been prepared and characterized to generate a functional model for nickel(II) phosphoesterase enzymes. The complex, [Ni2(L1)(μ-OAc)(H2O)2](ClO4)2·H2O, was characterized by microanalysis, X-ray crystallogr...

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Principais autores:	Adolfo Horn Jr., Daniel Englert, Asha E. Roberts, Peter Comba, Gerhard Schenk, Elizabeth H. Krenske, Lawrence R. Gahan
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Frontiers Media S.A. 2018-09-01
coleção:	Frontiers in Chemistry
Assuntos:	nickel phosphoesterase magnetism DFT kinetics mechanism
Acesso em linha:	https://www.frontiersin.org/article/10.3389/fchem.2018.00441/full
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