Crystal structure of bis[cis-(1,4,8,11-tetraazacyclotetradecane-κ4N)bis(thiocyanato-κN)chromium(III)] dichromate monohydrate from synchrotron X-ray diffraction data

The structure of the complex salt, cis-[Cr(NCS)2(cyclam)]2[Cr2O7]·H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane, C10H24N4), has been determined from synchrotron data. The asymmetric unit comprises of one [Cr(NCS)2(cyclam)]+ cation, one half of a Cr2O72− anion (completed by inversion symmetry) and...

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Detalhes bibliográficos

Principais autores:	Dohyun Moon, Masahiro Takase, Takashiro Akitsu, Jong-Ha Choi
Formato:	Artigo
Idioma:	Inglês
Publicado em:	International Union of Crystallography 2017-01-01
coleção:	Acta Crystallographica Section E: Crystallographic Communications
Assuntos:	crystal structure cyclam chromium(III) complex thiocyanate ligand cis-V conformation dichromate anion hydrogen bonding synchrotron radiation
Acesso em linha:	http://scripts.iucr.org/cgi-bin/paper?S2056989016020120
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