Metal-free hydroarylation of the side chain carbon–carbon double bond of 5-(2-arylethenyl)-3-aryl-1,2,4-oxadiazoles in triflic acid

The metal-free reaction of 5-(2-arylethenyl)-3-aryl-1,2,4-oxadiazoles with arenes in neat triflic acid (TfOH, CF3SO3H), both under thermal and microwave conditions, leads to 5-(2,2-diarylethyl)-3-aryl-1,2,4-oxadiazoles. The products are formed through the regioselective hydroarylation of the side ch...

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Principais autores:	Anna S. Zalivatskaya, Dmitry S. Ryabukhin, Marina V. Tarasenko, Alexander Yu. Ivanov, Irina A. Boyarskaya, Elena V. Grinenko, Ludmila V. Osetrova, Eugeniy R. Kofanov, Aleksander V. Vasilyev
格式:	Artigo
語言:	Inglês
出版:	Beilstein-Institut 2017-05-01
叢編:	Beilstein Journal of Organic Chemistry
主題:	Friedel–Crafts reaction hydroarylation oxadiazoles superelectrophilic activation triflic acid
在線閱讀:	https://doi.org/10.3762/bjoc.13.89
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