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Radical character quenches luminescence in the all-hydrocarbon radical benzoBDPA

We have synthesized and characterized a benzannulated analog, bBDPA, of the well-known stable radical bis(diphenylene)phenylallyl (BDPA). Benzannulation gives rise to fluorescence in the closed-shell precursor molecule bBDPAH, but luminescence is quenched in the radical species. We detail the synthe...

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Principais autores: Adrian R. Birge, Matthew J. Piper, Karl J. Painter, Graham T. Sazama
Format: Artigo
Sprog:Inglês
Udgivet: Elsevier 2022-01-01
Serier:Results in Chemistry
Fag:
Organic Radical
Luminescence
Fluorescence
Benzannulation
BDPA
Stable radicals
Online adgang:http://www.sciencedirect.com/science/article/pii/S2211715622001126
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