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Molecular entanglement can strongly increase basicity

Abstract Brønsted basicity is a fundamental chemical property featured by several kinds of inorganic and organic compounds. In this Review, we treat a particularly high basicity resulting from the mechanical entanglement involving two or more molecular subunits in catenanes and rotaxanes. Such entan...

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Principais autores: Giorgio Capocasa, Federico Frateloreto, Matteo Valentini, Stefano Di Stefano
Formato: Artigo
Idioma:Inglês
Publicado: Nature Portfolio 2024-05-01
Series:Communications Chemistry
Acceso en liña:https://doi.org/10.1038/s42004-024-01205-3
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