Transition metal complexes with asymmetric tridentate peripheral organosilyl ligands: their impact in homogeneous catalysis

Silyl-based tridentate ligands [SiL2]n− (n = 1, 2; L = PR3, NR2 or other groups) have emerged over the last decades as a versatile class of ligands for transition metal (TM) chemistry. TM–(κ3-Si,L2) complexes display unique structural features and reactivity that arise directly from the incorporatio...

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Autori principali:	María Batuecas, Luis A. Oro, Francisco J. Fernández-Álvarez
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	Frontiers Media S.A. 2026-03-01
Serie:	Frontiers in Chemistry
Soggetti:	asymmetric tridentate ligands homogenous catalysis organosilyl polydentate ligands pincer ligands transition metal-silyl complexes tridentate silyl ligands
Accesso online:	https://www.frontiersin.org/articles/10.3389/fchem.2026.1804159/full
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