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Stereoselective Synthesis of Bicyclo[3.1.1]Heptane Derivatives via Intramolecular Photocycloaddition Reaction

Optically active 1,3-bridged cyclobutanes 10 of the bicyclo[3.1.1]heptane ring system and 1,2-bridged cyclobutanes 11 of the bicyclo[3.2.0]heptane ring system were produced by UV irradiation of α,β,γ,δ-unsaturated esters 9a and 9c-f. The preference of endo -stereochemistry at C-6 bridged head was ob...

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Autori principali: Kiyoshi Honda, Mari Konishi, Manabu Kawai, Akihisa Yamada, Yasuhiko Takahashi, Yujiro Hoshino, Seiichi Inoue
Natura: Artigo
Lingua:Inglês
Pubblicazione: SAGE Publishing 2012-04-01
Serie:Natural Product Communications
Accesso online:https://doi.org/10.1177/1934578X1200700410
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