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Activation of Primary and Secondary Benzylic and Tertiary Alkyl (sp3)C-F Bonds Inside a Self-Assembled Molecular Container

Alkyl fluorides are generally regarded as chemically inert. However, several literature examples describe the activation of alkyl (sp3)C-F bonds via strong Brønsted or Lewis acids under harsh conditions. We here report that catalytic amounts of the self-assembled resorcinarene capsule are able to ac...

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Autori principali: Jesper M. Köster, Daniel Häussinger, Konrad Tiefenbacher
Natura: Artigo
Lingua:Inglês
Pubblicazione: Frontiers Media S.A. 2019-01-01
Serie:Frontiers in Chemistry
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Accesso online:https://www.frontiersin.org/article/10.3389/fchem.2018.00639/full
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