Electron and hydrogen self-exchange of free radicals of sterically hindered tertiary aliphatic amines investigated by photo-CIDNP

The photoreactions of diazabicyclo[2,2,2]octane (DABCO) and triisopropylamine (TIPA) with the sensitizers anthraquinone (AQ) and xanthone (XA) or benzophenone (BP) were investigated by time-resolved photo-CIDNP (photochemically induced dynamic nuclear polarization) experiments. By varying the radica...

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Autori principali:	Martin Goez, Isabell Frisch, Ingo Sartorius
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	Beilstein-Institut 2013-02-01
Serie:	Beilstein Journal of Organic Chemistry
Soggetti:	amines CIDNP electron transfer free radicals hydrogen transfer ketones kinetics photochemistry self-exchange
Accesso online:	https://doi.org/10.3762/bjoc.9.46
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