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A Study on the Direct Esterification of Monoalkylphosphates and Dialkylphosphates; The Conversion of the Latter Species to Trialkylphosphates by Alkylating Esterification

The microwave (MW)-assisted direct esterification of certain P-acids is a green method. Quantum chemical calculations revealed that the activation enthalpy (Δ<i>H</i><sup>#</sup>) for the exothermic monoalkylphosphate → dialkylphosphate transformation was on the average 156.6 kJ mol<sup>−1</sup>, wh...

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Bibliografische Detailangaben
Hauptverfasser: Péter Ábrányi-Balogh, Nikoletta Harsági, László Drahos, György Keglevich
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI AG 2022-07-01
Schriftenreihe:Molecules
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Online-Zugang:https://www.mdpi.com/1420-3049/27/15/4674
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