A Study on the Direct Esterification of Monoalkylphosphates and Dialkylphosphates; The Conversion of the Latter Species to Trialkylphosphates by Alkylating Esterification
The microwave (MW)-assisted direct esterification of certain P-acids is a green method. Quantum chemical calculations revealed that the activation enthalpy (Δ<i>H</i><sup>#</sup>) for the exothermic monoalkylphosphate → dialkylphosphate transformation was on the average 156.6 kJ mol<sup>−1</sup>, wh...
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| Format: | Artigo |
| Sprache: | Inglês |
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MDPI AG
2022-07-01
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| Schriftenreihe: | Molecules |
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| Online-Zugang: | https://www.mdpi.com/1420-3049/27/15/4674 |
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