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Development of an Efficient Stereoretentive Para‐Claisen‐Cope Rearrangement

A stereoretentive para‐Claisen‐Cope rearrangement of chiral aryl‐allyl ethers is reported, achieving near‐perfect chirality transfer thereby furnishing products with exceptional enantiomeric excess (up to > 98% ee) as single regioisomers. This transformation is operationally simple, air‐ and moistur...

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I tiakina i:
Ngā taipitopito rārangi puna kōrero
Ngā kaituhi matua: Johanna Breinsperger, Maximilian Kaiser, Nicolas Kratena, Peter Gärtner
Hōputu: Artigo
Reo:Inglês
I whakaputaina: Wiley-VCH 2025-11-01
Rangatū:ChemistryEurope
Ngā marau:
Urunga tuihono:https://doi.org/10.1002/ceur.202500110
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