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Development of an Efficient Stereoretentive Para‐Claisen‐Cope Rearrangement

A stereoretentive para‐Claisen‐Cope rearrangement of chiral aryl‐allyl ethers is reported, achieving near‐perfect chirality transfer thereby furnishing products with exceptional enantiomeric excess (up to > 98% ee) as single regioisomers. This transformation is operationally simple, air‐ and moistur...

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Principais autores: Johanna Breinsperger, Maximilian Kaiser, Nicolas Kratena, Peter Gärtner
Formato: Artigo
Idioma:Inglês
Publicado: Wiley-VCH 2025-11-01
Series:ChemistryEurope
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Acceso en liña:https://doi.org/10.1002/ceur.202500110
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